Oligosaccharide synthesis with

K. Demuth, H. J. Jordening, and K. Buchholz, Oligosaccharide synthesis with dextransucrase, in S. Bielecki, J. Tramper, and J. Polak, (Eds.), Food Biotechnology, Elsevier Science, Amsterdam, 2000, pp. 123-135. 

Prospects for solid-phase oligosaccharide synthesis with minimum manipulation of protective groups or eliminating such a need altogether... 

Glycoside and Oligosaccharide Synthesis with Unprotected Glycosyl Donors Based on the Remote Activation Concept... 

Scheme 4.19 Solid-phase oligosaccharide synthesis with glycosyl donors in solution.

It is the intention of this section to present recent advances in the the art of modern oligosaccharide synthesis, with particular emphasis on methods for the stereoselective assembly of 2-deoxyglycosides. The strengths of the various chemical methodologies will be discussed in a selected number of examples. 

Schmidt RR, Jung K-H. Oligosaccharide synthesis with trichloroacetimidates. In Preparative Carbohydrate Chemistry. Hanessian S, ed. 1997. Marcel Dekker, New York. pp. 283-312. 

Mogemark M, Elofsson M, Kihlberg J. Huorinated protective 82. groups for on-resin quantification of solid-phase oligosaccharide synthesis with 19F NMR spectroscopy. ChemBioChem 2002 3 1266-1269. 

Plante OJ, Andrade RB, Seeberger PH. Synthesis and use of gly-cosyl phosphates as glycosyl donors. Org. Lett. 1999 1 211-214. Plante OJ, Palmacci ER, Andrade RB, Seeberger PH. Oligosaccharide synthesis with glycosyl phosphate and dithiophosphate triesters as glycosylating agents. J. Am. Chem. Soc. 2001 123 9545-9554. 

Fructofuranose is found in probably the most well-known and commercially available of all carbohydrates, sucrose. Various derivatives of sucrose are also known in nature, e.g. fatty acid derivatives [91] and agrocinopines [92]. Fructo-furanosides are also present in various plant and bacteria polysaccharides, most often as fructans, but sometimes as a singular component in repeating units [2, 93]. Syntheses of sucrose or derivatives thereof are not very frequent [41, 94-96], and oligosaccharide synthesis with fructofuranosyl donors are even more scarce. 

Oligosaccharide synthesis with tri-chloroacetimidates] general aspects, 290 glycopeptide, 306 glycosyl phosphates, 294, 307, 308 hexasaccharide, 299 inverse procedure, 294 kinetic, thermodynamic effects, 293 Lewis acid catalysis, 289 neighboring group participation,... 

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