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Oligosaccharide Synthesis by Remote Activation O-Protected 3-Methoxy-2-pyridyloxy MOP Glycosyl Donors

Oligosaccharide Synthesis by Remote Activation O-Protected 3-Methoxy-2-pyridyloxy (MOP) Glycosyl Donors [Pg.413]

Thioglycosides are also used as glycosyl donors [7]. In contrast with glycosyl bromides and trichloroacetimidates, thioglycosides are more stable under most protection and deprotection conditions. Unlike imidates and bromides, which have to be prepared just [Pg.414]

Despite the great deal of progress made in the chemical synthesis of oligosaccharides, there is still room for innovation and improvement over existing methods. The need for rapid and efficient construction of oligosaccharides has dramatically increased owing to the recent advances in glycobiology and related research fields [21], [Pg.415]


Lou, B, Huynh, H K, Hanessian, S, Oligosaccharide synthesis by remote activation O-protected 3-methoxy-2-pyridyloxy (MOP) glycosyl donors. In Preparative Carbohydrate Chemistry, Hanessian, S, Ed., Marcel Dekker, New York, pp. 413-430, 1997. [Pg.187]




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3-Methoxy-2-pyridyloxy

3-Methoxy-2-pyridyloxy activation

3-Methoxy-2-pyridyloxy glycosyl donors

3-Methoxy-2-pyridyloxy synthesis

Activated glycosyl donor

Activity, glycosyl

Donor synthesis

Glycosyl donor

Glycosyl oligosaccharide synthesis

Glycosyl synthesis

Glycosylated synthesis

MOP glycosyl donor

MOPS

Mopping

O-Protected 3-Methoxy-2-pyridyloxy Glycosyl Donors

O-donor

O-glycosylated

O-protection

Oligosaccharide glycosylation

Remote

Remote activation

Remote active

SYNTHESIS 2-methoxy

Synthesis protection

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