Oligopyridines, coordination chemistry

Coordination bonds, between transition metal atoms and ligating atoms, 27 72-76 Coordination chemistry, of oligopyridines, see Oligopyridines, coordination chemistry Coordination complexes covalent binding in, 5 13-15 fluorocyclic derivatives, 15 346-368 Coordination compounds... 

Oligophenanthrolines, 46 176 Oligophosphates, 4 37-41 glasses, 4 38-41 Oligopyridines, 46 175, 176 coordination chemistry, 30 69-121, see also specific compound bonding modes, 30 72-76 history, 30 69-71 nomenclature, 30 71 stabilization, 30 71-72 a w-Oligosilanediols, 42 220-222 Omadine, 36 39... 

Coordination chemistry of 2.2 6. 2"-terpyridine and higher oligopyridines. Adv. Jnorg. Chem. Radiochem. 30, 69 (1986). 

The Coordination Chemistry of 2,2 6, 2"-Terpyridine and Higher Oligopyridines E. C. Constable... 

It is also apparent that complexes of 2,2 6, 2"-terpyridine differ in significant, and interesting, ways from those of 2,2 -bipyridine. Accordingly, a treatment of the coordination chemistry of 2,2 6, 2"-terpyridine and the higher oligopyridines is felt to be justified and timely. 

The archetypal macrocyclic oligopyridine is cyclosexipyridine (Fig. 28). The synthesis of this molecule was achieved by Newkome and co-workers (350). The elegant synthesis reported appears to be low-yield, and, as yet, no coordination chemistry has been reported. However, 4,4" -diaryl derivatives... 

Constable, E.C. (1994) Metallosupramolecular chemistry Chem. Ind., 56-59 Constable, E.C, Cargill Thompson, A.M.W. and D.A. Tocher (1992) Into the third dimension of coordination chemistry towards starburst arrays in Supramolecular Chemistry Eds Balzani, V. and De (Zola, L. Klewer Academic Press, Dordrecht 219-233 Constable, E.C, Cargill Thompson, A.M.W. and D.A. Tocher (1992) Synthesis, characterisation and spectroscopic properties of ruthenium(II)-2,2 6, 2"-terpyridine coordination triades. X-Ray structures of 4 -(A,A-dimethylamino)-2,2 6, 2"-terpyridine and w(4 -(A,A-dimethylamino)-2,2 6, 2"-terpyridine)ruthenium(II) hex uoro-phosphate acetonitrile solvate New J. Chem., 16, 855-867 Krohnke, F (1976) The specific synthesis of pyridines and oligopyridines Synthesis, 1-24... 

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