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Olefin epoxidation oxygen rebound mechanism

Building on an earlier conclusion, epoxidations of various olefins by this manganese catalyst revealed at least two mechanisms but not the oxygen rebound mechanism. To extend these studies, the epoxidation of cis-stilbene was performed with 2% H2O2 under an atmosphere of 2 (Schemes 3.8 and 3.10). The deviation in the content from 100% in case of cis-stilbene oxide approximates... [Pg.139]

See other pages where Olefin epoxidation oxygen rebound mechanism is mentioned: [Pg.2188] [Pg.65] [Pg.120] [Pg.132] [Pg.137] [Pg.138] [Pg.2187] [Pg.484] [Pg.21] [Pg.89] [Pg.181] [Pg.146] [Pg.258] [Pg.68]