Octakis phthalocyaninato

A novel tetraazaporphyrinato (TAP) and phthalocyaninato mixed het-eroleptic rare-earth compound, LnPc (TAP) with photochromic and electrochromic features has been readily synthesized by a one-pot reaction using Eu(acac)3-wH20, metal-free phthalocyanine H2Pc (Pc = 2,3,9,10,16,17,23,24-octakis(decyloxy)phthalo-... 

We deal here with an interesting metallo Pc and ball-type metallo Pcs as the only examples in the literature for NLO and OL. [Octakis(mercaptopropylisobutyl-POSS)phthalocyaninato]Co(II),Cu(II), and Zn(II) complexes were investigated and compared with respect to NLO and OL properties [58]. These compounds showed that the change of the central metal ion in Pc leads to the variation of the relevant NLO and OL properties. All metallo Pcs with Co(II), Cu(II), and Zn(II) reveal NL absorption. CuPc exhibits the largest NL absorption, while CoPc and ZnPc... 

M(Pc)2 MPc[Pc(OC8H17)8] Bis(phthalocyaninato) rare earth complex Heteroleptic (phthalocyaninato) [2,3,9,10,16,17,23,24-octakis(octyloxy)-phthalocyaninato] rare earth double-decker complex... 

Finally, several, novel, star-shaped octakis(stilbenoid phthalocyaninato) zinc complexes ((7) R = or R, = 3, 6) were synthesized. The thermal behavior of the twenty-four-chained complex was not studied (R ), but that with hexyloxy side chains (R, n = 6) was found to self-organize into a Coin phase at room temperature up to 220 °C. 

Structure of an octakis-substituted i>w(phthalocyaninato)lanthanide(III) sandwich... 

Xie, D., Y. Jiang, J. Jiang, Z. Wu, and Y. Li (2001). Gas sensitive Langmuir-Blodjectt films based on erbium bis[octakis(octyloxy )phthalocyaninato) complex. Sensor Actuator B Chem. 77, 260-263. 

Victor Akpe, Hjalmar Brismar, Tebello Nyokong, Osadebe, P. O. Photophysical and photochemical parameters of octakis (benzylthio)phthalocyaninato zinc, aluminum and tin Red shift index concept in solvent effect on the ground state absorption of zinc phtha-locyanine derivatives. 

Fig. 10 High resolution XPS spectra of the S(2p) region of (a) MnOPhTPc-SAM and (b) MnODTPc-SAM. Pass energy 40 eV, number of scans 5. The structures of the Pcs are shown on top of each XPS spectra MnOPhTPc = octakis(phenylthio) phthalocyaninato manganese(III) (Ac). MnODTPc = octaMs(decylthio) phthalocyaninato manganese(III)(Ac). Ac = acetate. Reproduced with permission from Ref. [46]...

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