O2 for mono-oxygenation

Metal-induced reductive activation of O2 for mono-oxygenation 

Reaction mimic for the cytochrome P-450 mono-oxygenase/reductase system [Fe HMeCN)l+/O2/PhNHNHPh/substrate] 

Chapter 4 discusses the ability of FeH(MeCN) to activate HOOH for monooxygenase and dehydrogenase chemistry, for example. 

A separate study has shown that PhNHNHPh is an effective reaction mimic for the flavin cofactors in xanthine oxidases and cytochrome P-450 reductases, and in combination with O2 yields HOOH. 

Reaction Mimic for the Methane Mono-oxygenase Proteins Fe DPAH)2/O2lPhNHNHPh/substrate 

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