Nyquist plots steel

Consider first the corrosion of low alloy steel in HC1 per se, i.e. before the addition of organic inhibitors. As shown in Figures 1 and 2 for N80 steel in 15% and 28% HC1 at 65 C, Nyquist plots for steel in concentrated HC1 typically have only one distinct feature a single capacitance loop (a loop above the Z axis) with a hint of a second capacitance loop at lower frequencies. The low-frequency loop is more fully developed in 28% HC1 than in 15% HC1. Mass transport limitations are not evident except under extreme conditions, e.g. above 28% HC1 and 65 C. 

Flash Rusting (Bulk Paint and "Wet" Film Studies). The moderate conductivity (50-100 ohm-cm) of the water borne paint formulations allowed both dc potentiodynamic and ac impedance studies of mild steel in the bulk paints to be measured. (Table I). AC impedance measurements at the potentiostatically controlled corrosion potentials indicated depressed semi-circles with a Warburg diffusion low frequency tail in the Nyquist plots (Figure 2). These measurements at 10, 30 and 60 minute exposure times, showed the presence of a reaction involving both charge transfer and mass transfer controlling processes. The charge transfer impedance 0 was readily obtained from extrapolation of the semi-circle to the real axis at low frequencies. The transfer impedance increased with exposure time in all cases. 

Figure 2. Nyquist plot for mild steel in standard paint.

Figure 10. Nyquist plots for bitumen coated mild steel. Day 0 and Day 50.

So far, the ionic conductivity of most ILs has been measured by the complex impedance method [116], In this method, charge transfer between carrier ions and electrode is not necessary. Therefore platinum and stainless steel are frequently used as blocking electrodes. However, it is often difficult to distinguish the resistance and dielectric properties from Nyquist plots obtained by the impedance measurement. In order to clarify this, additional measurements using non-blocking electrodes or DC polarization measurement are needed. 

Itagaki et al. [120] used EIS to investigate the electrochemical properties of the rust film membrane formed on low alloy steels. The electrochemical impedance of the actual rust film membrane formed by wet-dry cycles showed the capacitive semicircle on Nyquist plot corresponding to a single time constant. The time constant of the capacitive semicircle was found composed of the rust film resistance and the film capacitance. The value of rust film resistance was shown to depend on the alloying elements in weathering steel and it was shown that the... 

Figure 4. 5. Nyquist plot of impedance data for 1018 steel in HCl-acidified 3% NaQ (pH = 3). Expostire time = 28h, = -0.682V (SCE).

Figure 4.4.55 presents the real vs. imaginary components of the electrochemical-mechanical impedance response measured for an FIY80 steel specimen of geometry shown in Figure 4.4.53 immersed in 3.5 wt % NaCl. Due to the form of Eq. (177), these plots are somewhat more complex than a conventional Nyquist plot. Nevertheless, these data are amenable to standard methods of electrical... 

Nyquist plots recorded using two-electrode symmetric supercapacitor in 0.5 M Na2S04 aqueous solution. The electrode layers with active surface area of 4.0 cm are composed of BP2000 carbon particles as active material and stainless steel as current collector material. AC frequency range = 0.3Hz to 122KHz. (Source Zhang, L. and J. Zhang. 2011. NRC unpublished data. 

Figure 3.11 shows Nyquist plots of a AISI 1030 steel immersed in phosphoric add H3PO4) containing butanol and thiosemicarbonate (TSC) at room temperature. These data is for a charge-control mechanism with and without the... 

Figure 3.11 Experimental Nyquist plots for AISI1030 steel in 35% H3PO4 + 6% butanol -I- TSC inhibitor at room temperature [26].

Figure 9-12. Nyquist plots of mild steel in a model solution with different inhibitors after 30 min nitrile (triacetic acid) (NTA) phospho-nomethyl-iminodi (acetic acid) (MPIDA), di(phosphonomethyl)-glycine (DMPG), nitrilotri(methyl-phosphonic acid) (ATMP).

Figure 9-13. Nyquist plots of mild steel in the model solution with DMPG for different times DMPG di(phosphonomethyl)glycine.

The constant phase element can be found for electrochemical behavior in both electrolytes. The unique identification came from the depressed semicircle in Nyquist plots [45]. The existence of a Warburg impedance in the 3.5% NaCl immersion test indicated diffusion control (mass transfer) in that medium. The signature of Warburg impedance is found in Nyquist plots exhibiting a 45° curve in the low frequency region (see Fig. 31.5). Clearly, the polarization resistance did not decrease much for zk/s in 0.1 M HCl even after 8 weeks of immersion. However, there was a significant decrease in 3.5% NaCl. The double layer capacitance for the sample containing a polyaniline film on mild steel was always smaller in 0.1 M HCl environments than in 3.5% NaCl. 

The measured frequency characteristics of electrochemically produced iron and S235JR steel in corrosive environment of 0.5M NaCl solution are presented in the form of Nyquist diagrams (Fig. 14) and Bode plots of impedance spectra (Fig. 15). 

Figure 9-33. a) Nyquist and b) Bode plots of carbon steel frequency response in various Ca /HEDP containing solutions (blank 0.5 mol dm NaC104, pH 7 Chedp= 3 X10 mol dm ) (Felhosi et al., 1999 a). (Reproduced by permission.) Re(Z) real part of impedance, Im(Z) imaginary part of impedance, chi-s chi-squared. 

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