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Nucleophilic aliphatic leaving-group effects

The Skv I radical chain mechanism lor nucleophilic substitution [I70. as illustrated generally in eqs (2.64a-c), has been absent from our discussions. This mechanism has been shown to occur itt malty displacement reactions of leaving groups front both aromatic and aliphatic substrates. I low ever, in most of the aliphatic eases the substrates have a nitro or nilrophcnyl group (or other effective electron acceptor) in the a-position to the leaving group. The combination of I he nucleophile with the radical from the substrate must also lot m a relatively stable radical-anion in step 2.6lb. which is capable of propagating the chain... [Pg.59]

See other pages where Nucleophilic aliphatic leaving-group effects is mentioned: [Pg.154]    [Pg.198]    [Pg.860]    [Pg.30]    [Pg.23]    [Pg.284]    [Pg.87]    [Pg.314]    [Pg.30]    [Pg.154]    [Pg.198]    [Pg.2043]    [Pg.67]    [Pg.366]    [Pg.38]    [Pg.154]    [Pg.198]    [Pg.249]    [Pg.294]    [Pg.163]    [Pg.1577]    [Pg.224]    [Pg.508]    [Pg.86]    [Pg.108]    [Pg.653]    [Pg.101]    [Pg.82]    [Pg.97]    [Pg.131]    [Pg.82]    [Pg.82]   
See also in sourсe #XX -- [ Pg.323 ]

See also in sourсe #XX -- [ Pg.321 , Pg.322 ]

See also in sourсe #XX -- [ Pg.323 ]



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Leaving group effects

Nucleophile effects

Nucleophiles effectiveness

Nucleophiles groups

Nucleophilic aliphatic

Nucleophilic groups

Nucleophilic substitution reactions, aliphatic leaving group effects

Nucleophilicity effects

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