Nuclear reactions radioactive series

Californium is a synthetic radioactive transuranic element of the actinide series. The pure metal form is not found in nature and has not been artificially produced in particle accelerators. However, a few compounds consisting of cahfornium and nonmetals have been formed by nuclear reactions. The most important isotope of cahfornium is Cf-252, which fissions spontaneously while emitting free neutrons. This makes it of some use as a portable neutron source since there are few elements that produce neutrons all by themselves. Most transuranic elements must be placed in a nuclear reactor, must go through a series of decay processes, or must be mixed with other elements in order to give off neutrons. Cf-252 has a half-life of 2.65 years, and just one microgram (0.000001 grams) of the element produces over 170 mhhon neutrons per minute. 

The isotopes of thorium include mass numbers 223-234. 232Th has a half-life of 1.39 x 1010 years, See also Radioactivity. It emits an alpha-particle and forms meso-thorium 1 (radium-228), which is also radioactive, having a half-life of 6.7 years, emitting a beta-particle. Since 2 2Th captures slow neutions to form, by a series of nuclear reactions, >>U which is fissionable, thorium can be used as a fuel for nuclear reactors of the breeder type. Thorium occurs in earth minerals, an average content estimated at about 12 ppm. Findings of hc Apollo 11 space flight indicated that thorium concentrations in some lunar rocks are about the same as the concentrations in terrestrial basalts. 

The element francium is formed in the natural radioactive decay series and in nuclear reactions. All its isotopes are radioactive with short half-lives. The ion behaves as would be expected from its position in the group. 

A series of nuclear reactions that begins with an unstable nucleus and results in the formation of a stable nucleus is called a radioactive decay series. As you can see in Figure 25-11, uranium-238 first decays to thorium-235, which in turn decays to protactinium-234. Decay reactions continue until a stable nucleus, lead-206, is formed. 

The disintegration of a radioactive nucleus is often the beginning of a radioactive decay series, which is a sequence of nuclear reactions that ultimately result in the formation of a stable isotope. Table 23.3 shows the decay series of naturally occurring uranium-238, which involves 14 steps. This decay scheme, known as the uranium decay series, also shows the half-lives of all the products. 

It is important to be able to balance the nuclear reaction for each of the steps in a radioactive decay series. For example, the first step in the uranium decay series is the decay of uranium-238 to thorium-234, with the emission of an a particle. Hence, the reaction is... 

Nuclei differ in their stability, and some are so unstable that they undergo radioactive decay. The ratio of the number of neutrons to number of protons (N/Z) in a nucleus correlates with its stability. Calculate the N/Z ratio for (a) Sm (b) Fe (c) °Ne (d) ° Ag. (e) The radioactive isotope decays in a series of nuclear reactions that includes another uranium isotope, and three lead isotopes, Pb, °Pb, and ° Pb. How many neutrons, protons, and electrons are in each of these fi ve isotopes ... 

This is understood to mean that a neutron is absorbed by a nucleus of 13AI and gamma radiation is emitted, resulting in the formation of a product nucleus f Al. The product nucleus of a nuclear reaction can be either stable or radioactive. If the product nuclide is radioactive, it will eventually decay to a different nuclide. The most common modes of decay are emission of alpha particles, beta particles, and gamma rays other particles or radiations can also be emitted in radioactive decay, but they are of little analytical utility and will not be discussed here. Radioactive decay may involve a single-step transformation or may proceed through a series of steps. An example of the former is... 

Some nuclei cannot gain stability by a single emission. Consequently, a series of successive emissions occurs as shown for uranium-238 in A FIGURE 21.3. Decay continues until a stable nucleus—lead-206 in this case—is formed. A series of nuclear reactions that begins with an unstable nucleus and terminates with a stable one is known as a radioactive series or a nuclear disintegration series. Three such series occur in nature uranium-238 to lead-206, uranium-235 to lead-207, and thorium-232 to lead-208. 

The disintegration of a radioactive nucleus is often the beginning of a radioactive decay series, which is a sequence of nuclear reactions that ultimately result in the... 

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