Novel Attempts and Methods for Forming Alane Reversibly

Novel Attempts and Methods for Forming Alane Reversibly 

The typical formation route for alane is through the chemical reaction of lithium alanate with aluminum chloride in diethyl ether  

Graetz et al. suggested that since direct formation of amine-alane such as alane triethyldiamine (A1F13-TEDA), works well but forms a strong Al—N bond [43], it may 

They proposed a route of regeneration of alane that involves the use of UAIH4 

Where NR3 represents an amine that forms a veak Al—N bond, such as triethylamine (NEt3) 

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Novel Attempts and Methods for Forming Alane Reversibly 269 Table 9.1 Different aluminium hydride structures and their space groups and unit cell parameters. 

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