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Nonheme iron monooxygenases

Subramanian V, CS Vaidyanathan (1984) Anthranilate hydroxylase from Aspergillus niger new type of NADPH-linked nonheme iron monooxygenase. J Bacteriol 160 651-655. [Pg.88]

Figure 3 Activation of O2 by 2-oxo-glutarate dependent nonheme iron monooxygenases... Figure 3 Activation of O2 by 2-oxo-glutarate dependent nonheme iron monooxygenases...
FUNCTIONAL MODEL SYSTEMS FOR NONHEME IRON MONOOXYGENASES... [Pg.181]

Oxygenations proceed at nonheme mono- and diiron centers in the presence of electron and proton donors that are important for activation of molecular oxygen. The presence of the efficient electron and proton donor systems is characteristic of the enzymatic systems. The most popular nonheme iron monooxygenase is soluble... [Pg.181]

NONHEME IRON MONOOXYGENASES OTHER THAN sMMO... [Pg.316]

Important nonheme iron monooxygenases other than sMMO are pterin-dependent enzymes and isopenicillin N synthase. Three enzymes are known as the pterin-dependent monooxygenases phenylalanine hydroxylase (PAH), tyrosine hydroxylase (TH), and tryptophan hydroxylase (TPH). These enzymes perform metabolically important transformations, e,g, for the biosynthesis of neurotransmitters, and catalyze the reactions shown in Fig. 8. [Pg.316]

Chemical Models for Putative Reaction Intermediates of Nonheme Iron Monooxygenases... [Pg.347]

In contrast, a coordinatively unsaturated a-ketoglutarate ferrous complex Fe(II)(BF)(HB-3,5-Me2pz)3 was reported very recently [90]. The dioxygen oxidation of this ferrous complex forms a reactive species capable of epoxidizing olefin. The reaction mechanism of this system has not yet been elucidated, while the reactivity of this system is markedly high and is expected to be a clue in understanding the mechanism of a-keto acid dependent nonheme iron monooxygenase. [Pg.358]

Nonheme iron monooxygenases other than sMMO 316... [Pg.403]

See other pages where Nonheme iron monooxygenases is mentioned: [Pg.309]    [Pg.1907]    [Pg.1906]    [Pg.284]    [Pg.320]    [Pg.345]    [Pg.347]    [Pg.348]    [Pg.349]    [Pg.354]    [Pg.355]    [Pg.357]    [Pg.403]   


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Monooxygenase nonheme iron-containing

Nonheme

Nonheme Iron Monooxygenase

Nonheme Iron Monooxygenase

Nonheme iron

Nonheme iron-dependent monooxygenases

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