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Nonbonded resonance stabilization energies

Resonance effect is an energy stabilization due to delocalization of electrons in the bond network of the molecule and can be attributed to a mesomeric effect, i.e. the delocalization of Jt electrons on the jr orbital network, a hyperconjugation effect, i.e. a delocalization of a electrons in a ji orbital aligned with the o bond, and secondary mesomeric effects, such as repulsion of the ir electrons by nonbonded electrons on a substituent or solvent, or by time-dependent effects due to polarizabilities (for the last, the term electromeric effect is sometimes used). [Pg.145]


See other pages where Nonbonded resonance stabilization energies is mentioned: [Pg.229]    [Pg.98]    [Pg.142]    [Pg.169]    [Pg.39]    [Pg.545]    [Pg.475]    [Pg.607]    [Pg.584]    [Pg.584]    [Pg.168]    [Pg.109]    [Pg.109]    [Pg.7]    [Pg.94]    [Pg.296]    [Pg.109]    [Pg.607]    [Pg.109]    [Pg.230]    [Pg.280]    [Pg.8455]    [Pg.579]    [Pg.215]    [Pg.303]    [Pg.1222]    [Pg.198]   
See also in sourсe #XX -- [ Pg.209 ]




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