Non-natural ensembles

In other words, if we look at any phase-space volume element, the rate of incoming state points should equal the rate of outflow. This requires that be a fiinction of the constants of the motion, and especially Q=Q i). Equilibrium also implies d(/)/dt = 0 for any /. The extension of the above equations to nonequilibriiim ensembles requires a consideration of entropy production, the method of controlling energy dissipation (diennostatting) and the consequent non-Liouville nature of the time evolution [35]. 

The pairwise nature of the bond-boost makes this task easier since such traps would show up as a non-convexity of some of the biased effective pair potentials, which in the canonical ensemble can be taken to be the pairwise potential of mean force (PMF, denoted as V). Thus, assuming that V is approximately quadratic for lei safety condition can be enforced by setting Sa[Pg.92]

In this review, we begin with a treatment of the functional theory employing as basis the maximum entropy principle for the determination of the density matrix of equilibrium ensembles of any system. This naturally leads to the time-dependent functional theory which will be based on the TD-density matrix which obeys the von Neumann equation of motion. In this way, we present a unified formulation of the functional theory of a condensed matter system for both equilibrium and non-equilibrium situations, which we hope will give the reader a complete picture of the functional approach to many-body interacting systems of interest to condensed matter physics and chemistry. 

Nobel laureate in Physics) in 1924. In quantum mechanics, two ensembles which show the same distributions for all the observables are said to be in the same state. Although this notion is being introduced for statistical ensembles, it can also be applied to each individual microsystem (see, for example, ref. 8), because all the members of the ensemble are identical, non-interacting and identically prepared (Fig. 1.4). Each state is described by a state function, ip (see, for example, ref. 3). This state function should contain the information about the probability of each outcome of the measurement of any observable of the ensemble. The wave nature of matter, for example the interference phenomena observed with small particles, requires that such state fimctions can be superposed just like ordinary waves. Thus, they are also called wavefunctions and act as probability amplitude functions. 

Being illuminated the semiconductor is by no means at equilibrium. Nonetheless, under certains conditions both the electron ensemble and the hole ensemble, each one taken separately, may be assumed to be at equilibrium. Therefore, certain "electrochemical potential" is to be assigned to each ensemble separately these are called "quasi-Fermi levels", Fp and F. They, naturally, do not coincide with F, the difference depends on how far the non-equilibrium (light) concentration of corresponding current carriers declines from the equilibrium (dark) value. E g, for holes the difference equals to. 

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