Nitrosyl complexes technetium

Dinitrogen, Phosphine, Phosphite, and Related Complexes Complexes with Nitrogen Ligands Nitrosyl and Thionitrosyl Complexes Technetium(II)... 

Figures 7,8 shows plots of data for chromium and molybdenum nitrosyl species the slope with El(L) is essentially the same as for non-NO species. Thus, in Figure 7,8 [data from 10,31,32], a value for El(NO) is used which will cause the nitrosyl complexes to fit the correlation line. This yields El(NO + ) = 2.55 - 2.57 for both metal ions. Values in the range 1.2 -1.8, for El(NO" "), have been described by Clarke [33] for some technetium nitrosyl derivatives. This area would benefit from a detailed analysis.

Chromatography cyclophosphazenes, 21 46, 59 technetium, 11 48-49 Chromites, as spinel structures, 2 30 Chromium, see Tetranuclear d-block metal complexes, chromium acetylene complexes of, 4 104 alkoxides, 26 276-283 bimetallics, 26 328 dimeric cyclopentdienyl, 26 282-283 divalent complexes, 26 282 nitrosyls, 26 280-281 trivalent complexes, 26 276-280 adamantoxides, 26 320 di(/ >rt-butyl)methoxides, 26 321-325 electronic spectra, 26 277-279 isocyanate insertion, 26 280 substitution reactions, 26 278-279 [9]aneS, complexes, 35 11 atom... 

Complexes with Dioximes, Schiff Bases, and Other Nitrogen Ligands Complexes with Monodentate Phosphines and Related Ligands Complexes with Bidentate Phosphine, Arsine, and Related Ligands Complexes with Sulfur Ligands Nitrosyl and Thionitrosyl Complexes VII. Technetium(IV)... 

The first and only nitrosyl hydride has been prepared recently by the reduction of the complex MnBr(NO)2(PPh3)2 with sodium boro-hydride (170). It may be noted that reduction of the nitrosylcarbonyl (ir-C5H5)Cr(CO)(NO)Br does not give a Cr—H complex. A possible polynuclear technetium hydride [Tc(CO)4]3H has been discussed (186). Reduction of the complex CH3SCH2CH2SCH3Mo(CO)3l2 affords an unstable hydride (215). 

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