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Nitrogen nucleophiles catalysis, intramolecular attacks

Diamines of varying structure show rate enhancements of 20-200 fold, compared to monofunctional aliphatic amines, in nucleophilic reactions with N-acetylimidazole (Page and Jencks, 1972). These were attributed to intramolecular general base catalysis of proton removal from the attacking nitrogen, viz.. [Pg.19]

See other pages where Nitrogen nucleophiles catalysis, intramolecular attacks is mentioned: [Pg.324] [Pg.115] [Pg.131] [Pg.418] [Pg.115] [Pg.53] [Pg.39] [Pg.130] [Pg.542] [Pg.88] [Pg.114] [Pg.813] [Pg.160] [Pg.244] [Pg.244] [Pg.226] [Pg.113] [Pg.16]

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Catalysis intramolecular

Nitrogen nucleophile

Nitrogen nucleophiles

Nucleophile Nucleophilic attack

Nucleophile attack

Nucleophile catalysis

Nucleophile intramolecular

Nucleophiles attack

Nucleophiles catalysis, nucleophilic

Nucleophilic attack

Nucleophilic attack catalysis

Nucleophilic catalysis

Nucleophilic catalysis intramolecular

Nucleophilic intramolecular

Nucleophilicity nitrogen nucleophiles