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Nicolaou hydroxy-ketone reductive cyclic ether formation

Nicolaou hydroxy-ketone reductive cyclic ether formation [Pg.426]

Acid-catalyzed conversion of a ketone with a pendant hydroxyl group into a cyclic ether with net reduction of the carbonyl. [Pg.426]

The mechanism involves hemiketal formation followed by reduction of the oxocarbonium group  [Pg.426]


See also in sourсe #XX -- [ Pg.426 ]




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Cyclic 1,3-hydroxy

Cyclic ethers, formation

Cyclic formation

Cyclic ketones

Cyclic ketones, formation

Cyclic reduction

Ethere cyclic

Ethers cyclic

Ethers formation

Ethers ketones

Formate reductant

Formates reduction

Formats, cyclic

Hydroxy ethers

Hydroxy ethers formation

Hydroxy formation

Hydroxy ketones

Hydroxy ketones formation

Hydroxy ketones reduction

Ketones cyclic, reduction

Ketones formation

Nicolaou

Reduction etherate

Reduction formation

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