Nickel complexes phenoxy

Figure 12 Activation of phenoxy-imine nickel complexes by loss of a phosphine or pyridine ligand.

Mono(organo)nickel compounds, via oxidative addition, 8, 44 Monoorganotin hydroxides, preparation, 3, 850 Monoorganotin oxides, preparation, 3, 850 Mono(pentamethylcyclopentadienyl) actinide(IV) compounds, reactions, 4, 207 Mono(pentamethylcyclopentadienyl) lanthanide(III) compounds, synthesis and characteristics, 4, 66 Mono(pentamethylcyclopentadienyl) uranium(IV) sulfido complex, synthesis, 4, 207-208 Mono(phenoxy-aldehyde) trichlorides, with Zr(IV),... 

Shen and coworkers used Kawaguchi s phenoxy functionalised carbene ligand for the preparation of nickel(II) [62] and iron (II) [63] carbene complexes. Using the same deprotonation method — NaN(SiMe3)2— they attempted the synthesis of a mono-carbene nickel(II) complex that resulted in the formation of the homoleptic complex instead [62] (see Figure 4.16). Use of the correct stoichiometries significantly increased the yield. 

Figure 4.16 Synthesis of a homoleptic nickel(Il) carbene complex with a phenoxy functionalised NHC ligand.

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