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Nanoscale reaction vessels

Fiedler D, Leung DH, Bergman RG, Raymond KN (2005) Selective molecular recognition, C-H bond activation, and catalysis in nanoscale reaction vessels. Acc Chem Res 38 349... [Pg.121]

A. Simonyan, I. Gitsov, Linear-dendritic supramolecular complexes as nanoscale reaction vessels for green chemistry. Diels-Alder reactions between fullerene Cgo and polycydhc aromatic hydrocarbons in aqueous medium, Langmuir, 2008, 24, 11431. [Pg.174]

Nanoreactors are nanoscale reaction vessels that are able to encapsulate guests. It is proved that a confined nanoenvironment within a nanoreactor may infln-ence the reaction in terms of reactivity, selectivity, the reaction pathway, yield, kinetics, or mechanism and conversion. These features of nanoreactois are reminiscent of hydrophobic pockets in enzymes, which are capable of molecn-lar recognition and selective encapsulation of guests. Enzymes can reduce the energy of the transition states of key reaction intermediates selectively. Fnrlher-more, they accelerate reaction rates by increasing the local concentration. [Pg.161]

See other pages where Nanoscale reaction vessels is mentioned: [Pg.193]    [Pg.736]    [Pg.173]    [Pg.5723]    [Pg.703]    [Pg.5722]    [Pg.1299]    [Pg.156]    [Pg.156]    [Pg.43]    [Pg.193]    [Pg.736]    [Pg.173]    [Pg.5723]    [Pg.703]    [Pg.5722]    [Pg.1299]    [Pg.156]    [Pg.156]    [Pg.43]    [Pg.653]    [Pg.446]    [Pg.937]    [Pg.620]    [Pg.184]    [Pg.474]    [Pg.289]    [Pg.3067]    [Pg.390]   
See also in sourсe #XX -- [ Pg.156 ]



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