Nanoreactors nanostructure formation process

During the redox process connected with the coordination process, the character of chemical bonds changes. Therefore correlations of wave numbers of the changing chemical bonds can be applied as the characteristic of the nanostructure formation process in nanoreactor. 

As mentioned before, at two-dimensional growth circles that form petals and further more complex nanostructures resembling flowers can be formed [15], When being rolled, the circles formed can produce distorted semispheres or can serve as a basis for the transformation into a beady. During the redox process connected with the coordination process, the character of chemical bonds changes. Therefore correlations of wave numbers of the changing chemical bonds can be applied as the characteristic of the nanostructure formation process in nanoreactor. 

Kodolov V. I., Blagodatskikh 1.1., Lyakhovich A. M. et al. Investigation of the formation processes of metal containing carbon nanostructures in nanoreactors of polyvinyl alcohol at early stages. Chemical physics and mesoscopy, 2007. V. 9. Issue 4. p. 422 29. 

The formation processes of metal-containing nanostructures in carbon or carbon-polymeric shells in nanoreactors can be related to one t) e of reaction series using the terminology of the theory of linear dependencies of free energies (LFE) [16]. Then it is useful to introduce definite critical values for the volume, surface energy of nanoreactor internal walls, as well as the temperature critical value. When the ration Ig k/k is proportional -AAF/RT, the ratio WAV can be transformed into the following expression ... 

To carry out the processes based on the notions of nanochemistry, the directed energy action on the system is required, with the help of chemical particle field as well, for the transition fi-om the prepared near- transition state into the process product state (in our case - into nanostructures or nanocomposites). The perspective area of rranochemistry is the chemistry in nanoreactors. Nanoreactors can be compared with specific rrano-structures representing limited space regions in which chemical particles orientate creating transition state prior to the formation of the desired nanoproduct. Nanorectors have a definite activity, which predetermines the creation of the corresponding product. When nanosized particles are formed in nanoreactors, their shape and dimensions can be the reflection of shape and dimensions of the nanoreactor [5]. 

Because of the association of polymeric phase with metal containing phase the walls of nanoreactor participate in redox process with cover formation for metal containing clusters obtained [3-6], Metal/carbon nanocomposites will be more active than earbon or silicon nanostructures because their masses are bigger at identieal sizes and shapes. Therefore the vibration energy transmitted to the medium is also high. 

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