Nanoporous carbon Synthesis

Synthesis and Characterization of Nanoporous Carbon and Its Electrochemical Application to Electrode Material for Supercapacitors... 

Lee J. S., Joo S. H. and Ryoo R., Synthesis of mesoporous silicas of controlled pore wall thickness and their replication to ordered nanoporous carbons with various pore diameters. J. Am. Chem. Soc. 124 (2001) pp. 11S6-1157. 

J.S. Lee, S.H. Joo, and R. Ryoo, Synthesis of Mesoporous Silicas of Controlled Pore Wall Thickness and their Replication to Ordered Nanoporous Carbons with Various Pore Diameters. J. Am. Chem. Soc., 2002, 124, 1156-1157. 

S.B. Yoon, J.Y. Kim, and J.S. Yu, Synthesis of Highly Ordered Nanoporous Carbon Molecular Sieves from Silylated MCM-48 using Divinylbenzene as Precursor. Chem. Commun., 2001, 559-560. 

Lee, J., Han, S., and Hyeon, T. (2004). Synthesis of new nanoporous carbon materials using nanostructured silica materials as templates. J. Mater. Chem., 14, 478-86. 

Surfactant-mediated synthesis of Ft nanoparticles/nanoporous carbons composite... 

P-22 - Novel synthesis of nanoporous carbons using colloidal templates... 

P-22 - Novel synthesis of nanoporous carbons using colloidal templates S.B. Yoon, I.S. Shin and J.-S. Yu... 

Jun S, Joo SH, Ryoo R, Kruk M, Jaroniec M, Liu Z, Ohsuna T, Terasaki O (2000) Synthesis of new, nanoporous carbon with hexagonally ordered mesostructure. J Am Chem Soc 122 10712-10713... 

Fulvio PF, Hillesheim PC, Oyola Y, Mahurin SM, Veith GM, Dai S (2013) A new family of fluidic precursors for the self-templated synthesis of hierarchical nanoporous carbons. Chem Commun 49 7289-7291... 

Besides the investigation of monolithic carbons with well-ordered mesoporosity as CO2 sorbents, the synthesis of ordered mesoporous carbon films for CO2 capture (membrane gas separation) also attracts much interest. Noticeably, highly ordered mesoporous carbon with cubic Im3m symmetry has been synthesized successfully via a direct carbonization of self-assembled F108 (EOi32P05oEOi32) and RE composites obtained in a basic medium of non-aqueous solution [66]. Dai et al. [49] demonstrated a stepwise self-assembly approach to the preparation of large-scale, highly ordered nanoporous carbon films (Eig. 2.14). 

Hu M, Reboul J, Furukawa S, Torad NL, Ji Q, Srinivasu P, Ariga K, Kitagawa S, Yamauchi Y (2012) Direct carbonization of Al-based porous coordination polymer for synthesis of nanoporous carbon. J Am Chem Soc 134 2864-2867... 

Continuous mesoporous carbon thin films were fabricated by direct carbonization of sucrose-silica nanocomposite films and subsequent removal of the silica [236]. The mesoporous carbon film with uniform and interconnected pores had a surface area of 2603 mVg and a pore volume of 1.39 cmVg. Subsequently, nanoporous carbons with bimodal PSD centered at about 2 and 27 nm in diameter were prepared by using both the TEOS-derived silica network and the colloidal silica particles as templates [237]. Figure 2.33 illustrates the preparation pathway. The pore sizes of the carbon are determined by the sizes of the added silica particles and the silica network. As the colloidal silica particles are commercially available with different diameters (e.g., 20 to 500 nm), this dual template synthesis process provides an efficient route to preparing nanoporous carbons with a controllable hierarchical pore structure. 

Figure 20 (a) Schematic Uluslration of the synthesis of nanoporous carbon nanotubes through AAO-confined hydrogen-bonding self-... 

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