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Naming, acid anhydrides heterocyclic amines

Methods for the A-acylation of similar heterocycles, such as simple thiazolidinethiones, have been reported since 1977, namely acyl chlorides in miscellaneous conditions,586 or carboxylic acids under DCC-activation.60,61 However the easiest and most effective method involves acyl chlorides or carboxylic anhydrides in the presence of an amine.47 Applying that procedure on carbohydrate scaffolds Rollin and co-workers62 reported the synthesis of diverse /V-acylated OZTs. The reactions were performed with good yields and the /V-selective acylation was ascertained by NMR— namely the thiocarbonyl 13C chemical shift (Scheme 41). Thanks to the dual nature of the carbanion drifting in the reaction,596 60 no competitive formation of the thioester, as mentioned by Plusquellec el al. in the case of benzothiazole, was observed. [Pg.147]


See other pages where Naming, acid anhydrides heterocyclic amines is mentioned: [Pg.14]    [Pg.20]    [Pg.33]   
See also in sourсe #XX -- [ Pg.918 ]

See also in sourсe #XX -- [ Pg.918 ]

See also in sourсe #XX -- [ Pg.946 ]




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