Na line widths

Fig. 13.8 Dependences of the line width of Na atom emission on acoustic power for 2 M NaCl solutions with ethanol concentrations of 0.5 mM (asterisks), 1 mM (triangles) and 2 mM (closed circles). The Na line width without the addition of ethanol is denoted by open circles and has a maximum at 4.8 W...

The effect of atomic motion in the solid state on nuclear resonance line width is illustrated by the behavior of Na resonance from NaCl as a function of temperature 97). In Fig. 9 is shown the variation of the Na line width with temperature for pure NaCl and NaCl doped with an atomic fraction concentration of 6 X 10 of CdCU. As discussed in Section II,A,2 the low-temperature, rigid-lattice line width will narrow when the frequency of motion of the nuclei under observation equals the line width expressed in sec.-. The number of vacancies present should be equal to the concentration of divalent impurities and the jump frequency of Na+ is the product of the atomic vacancy concentration and the vacancy jump frequency... 

Fio. 9. Na line width as a function of temperature in NaCl. Solid curve is that for NaCl sample doped with molar concentration 6 X 10 of CdCl2 dashed curve is for pure NaCl sample (97). 

---