Multiple guests

Fig. 12 (A) Template-directed synthesis of capsule 15 with either (B) single or multiple guests (templates).95 (For color version of this figure,...

Multiple guests have further been used as kinetic templates for creating multicapsules with one guest per chamber (Fig. 13).92 The dynamic characteristics and the overall potential of such intriguing carceplexes have not been fully examined though there was some indication that (a) encapsulation of three molecules of methyl acetate inside 23 was cooperative and (b) encapsulated pyrazines would in 24 modulate each other s magnetic environment.92,94 It is also worth mentioning that from the synthetic standpoint the preparation of capsule 25 was accomplished in an excellent 30% yield.94... 

Research on organic semiconductor materials has resulted in remarkable progress and the introduction of material combinations using hosts and single or multiple guests or additional host materials [24-30]. This demand for simultaneous coevaporation or doping is often difficult to achieve in VTE, but easily achieved by OVPD. In the previous section we explained the OVPD process conditions essen-... 

The idea of multiple guest encapsulation can also be expressed in polymeric self-assembling capsules. When... 

Figure 13 Proposed binding model of multiple guests at the surface of a foldamer. (Reproduced from Ref. 44. Wiley-VCH, 2006.)...

For multiple guest species, the cage of type denoted by j is filled with the guest species ij. The grand partition function is obtained from replacement of the occupied guest by other kind of guest species (including removal of it) as... 

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