Multiple bonds main-group

Multiple Bonded Main Group-Main Group and Transition Metal-Main Group Complexes... 

The main use of organocadmium compounds is for the preparation of ketones and keto-esters, and their special merit lies in the fact that they react vigorously with acid chlorides of all types but add sluggishly or not at all to multiple bonds (compare addition of Grignard reagents to carbonyl groups). Some t3rpical syntheses are ... 

This fundamental discovery dramatically affected the whole chemistry of main-group elements. Subsequently, a series of new compounds with silicon element multiple bonds has been introduced. Within only a few years, stable silenes (silaethenes with a Si = C double bond) [8-11], silaimines Si = N [12-14], and silaphosphenes Si = P [15] were synthesized. As a pacemaker, silicon chemistry has exerted a strong influence on further areas of main-group chemistry a variety of stable molecules with Ge = Ge [16], P = P [17], As = As [18], P = C and P = C [19-22] bonds were subsequently isolated, and systems with cumulated double bonds P = C = P [23-25] are also known today. 

Multiple bonds between transition metals and bare main group elements links between inorganic solid state chemistry and organometallic chemistry. W. A. Herrmann, Angew. Chem., Int. Ed. Engl., 1986, 25,56 (115). 

In the second chapter, Phil Power continues his remarkable and continuously successful search for new main group metal multiple bonding. The chapter is entitled Multiple Bonding Between Heavier Group 13 Elements, and covers the astounding new developments that have occurred in this area in... 

For a recent review of struettrres of main group multiple bonds, see Power. P. P. Chem. Rev. 1999, 99. 3463. 

Multiple Bonding Involving the Heavier Main Group 3 Elements Al,... 

Multiple Bonding Involving Heavier Main Group Elements... 

HOMONUCLEAR MULTIPLE BONDING INVOLVING THE HEAVIER MAIN GROUP 3 ELEMENTS... 

Compounds that involve multiple bonding between main group 3 and 4 elements have received very little attention to date. It has been suggested for many years, however, that formally single bonds such as B—C52 and... 

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