Multiple bonding silicon-arsenic

Driess, Matthias, Silicon-Phosphorus and Silicon-Arsenic Multiple Bonds. 39 193... [Pg.466]

Silicon-Phosphorus and Silicon-Arsenic Multiple Bonds... [Pg.193]

Element-element bonds, addition to G-G multiple bonds arsenic—selenium bonds, 10, 782 boron—boron bonds, 10, 727 boron—sulfur bonds, 10, 778 B-S and B-Ge bonds, 10, 758 chalcogen—chalcogen additions, 10, 752 germanium—germanium bonds, 10, 747 germanium-tin bonds, 10, 780 overview, 10, 725-787 phosphorus—phosphorus bonds, 10, 751 phosphorus—selenium bonds, 10, 782 phosphorus-sulfur bonds, 10, 781 Se-Si and Se-Ge bonds, 10, 779 silicon-germanium bonds, 10, 770 silicon-phosphorus bonds, 10, 780 silicon-silicon bonds, 10, 734 silicon-sulfur bonds, 10, 779 silicon-tin bonds, 10, 770 tin-boron bonds, 10, 767 tin-tin bonds, 10, 748... [Pg.101]

In arsenic ylides, As—C multiple bonding seems to be strongly reduced and the nonbonding interactions are also likely to be less important. The proposed nonplanar geometry may well account for this. Because in silylated arsenic ylides the silicon atoms would meet with unfavorable... [Pg.228]