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Multi-Electronic Orbitals in the Crystal Field

However, the multi-electronic treatment brings in an additional effect the field applied to an electron by the other electrons from the multi-electrons orbitals. [Pg.180]

Therefore, in order to satisfy the Pauli principle of the orbital occupancies, for the multi-electrons orbitals in the crystal field there appears two effects of electronic repelling  [Pg.180]

Therefore, the consideration of the multi-electronic treatment of the resulting terms depending on the relation Dq/B between these factors appears as natural next step. [Pg.181]

For the case Dq B one has the situation of the strong crystal field, but in relation with B, because Dq still remains as a perturbation On the contrary, the case Dq B is treated as the weak crystal field. [Pg.181]

The practical difference in considering these cases is the order in which the two influences are considered firstly the strong one and subsequently the weak one. [Pg.181]


See other pages where Multi-Electronic Orbitals in the Crystal Field is mentioned: [Pg.180]   


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Electronic fields

Electrons in crystals

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The Crystal Field

The Orbitals

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