Mukaiyama, Teruaki

Mukaiyama, Teruaki. Challenges in Synthetic Organic Chemistry. Clarendon Press, Oxford. 1990. 

Sugi, Kiyoaki D. Nagata, Takushi Yamada, Tohru Mukaiyama, Teruaki, Chem. Lett., (6), 493-494(1997). 

The synthesis of Baccatin HI shown in Scheme 13.57, which was completed by a group led by the Japanese chemist Teruaki Mukaiyama, takes a different approach for the previous syntheses. Much of the stereochemistry was built into the B-ring by a series of acyclic aldol additions in Steps A through D. A silyl ketene acetal derivative... 

The author thanks Professor Teruaki Mukaiyama, Kitasato Institute, Japan, for helpful discussions. 

Submitted by Teruaki Mukaiyama and Ko1ch1 Narasaka.1 Checked by Kathleen Hug and Clayton H. Heathcock. 

Unlike the other N5 modifications described previously, a 5-azido thioglycoside was found to be less reactive than the simple amide as is clear from the measured relative reactivity values (RRVs) (Fig. 5.4) [59], However, it was subsequently reported by Teruaki Mukaiyama and coworkers that a 5-azido sialyl fluoride was more reactive than both the corresponding acetamide and the V,V-diacctyl derivatives toward activation with the combination of SnCl4 and AgB(C6F5)4, although this may be a consequence of the differing anomeric stereochemistries employed [60],... 

Teruaki Mukaiyama, of the Science University of Tokyo (andfdrmerly of the Tokyo Institute of Technology arid the University of Tokyo) is one of the foremost Jepartesechernists,whose work has hM asignlffcfilnt Impact on the development of the aldol reaction and on other areas of organic synthesis. 

Teruaki Mukaiyama Isamu Shiina Science University of Tokyo, Kagurazaka, Shinjuku-ku... 

Yukihiro Motoyama Teruaki Mukaiyama Kenneth A. Murray Andrew G. Myers AJdra Nakamura... 

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