Monothio p-diketonates

Chelate-forming ligands are widely represented amongst oxygen- and sulfur-containing donors [1, vol.2 112,934]. On their basis the following complexes have been isolated monothiocarboxylates 537 [1, vol.2], thio-oxalates 538 [934], and monothio-p-diketonates 539 [1, vol.2 935-937] ... 

Monothio-p-diketones and their metal complexes. S. E. Livingstone. Coord. Chem. Rev., 1971, 7, 59-80 (73). 

Complexes with Ligands containing Oxygen and other Donor Atoms. The e.s.r. spectra of liquid and frozen solutions of the oxovanadium(iv) monothio-P-diketonates [V0(CH(CSR )C0R2 ] (R R = Me, CF3, Ph, 2-thienyl, or p-naphthyl) have shown that they exist as simple monomers in solution. The formation constants of the 1 1 complex between and thiodiglycol-... 

Table 7 lists the dipole moments p, of some complexes of monothio-)S-diketones, RCSH=CHCOR (R = C3F7, C2F5) and CHF2). With increasing fluorine content of the R group the dipole moments increase for analogous complexes. Dipole moments of monothio-/f-diketona-to complexes have been recently reviewed. ... 

With monothio 1,3-diketones V0 2-C4H3S P room 1.972 probably dimeric 71M7... 

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