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Molybdenum oxytetrachlorid

Molybdenum oxytetrachloride is a dark green crystalline compound with a melting point of 100 to 101°. Infrared absorption (KBr disk) has been used to establish the absence of OH- and H20 in verification of the anhydrous state. A broad band appears in the 970-em.-1 region and reveals molyb-denum-to-oxygen bonding. The oxychloride reacts with thoroughly dried Nujol so that satisfactory infrared spectra cannot be obtained with this as a dispersion medium. When exposed to light, molybdenum oxytetrachloride forms a brown film on the surface of the ampule. Since this film is not formed when the ampules are stored in the dark, molybdenum oxytetrachloride is concluded to be photosensitive. [Pg.58]

Molybdenum oxytetrachloride has been prepared in limited quantities by several methods,1,2 most of which give low yields... [Pg.227]

Reactions of cyclo-octa-1,3-diene with molybdenum oxytetrachloride and tungsten oxytetrachloride have been carried out and the novel compounds (C8Hn)2-MoOClj and (CgHjj)2WOCl2 have been isolated Reactions of these products with mono, di-, and tri-hydroxyphenols have been studied. ... [Pg.344]

Molybdenum and tungsten oxytetrachlorides, M0OCI4 and WOCI4, react with anhydrous H2S in boiling benzene to form the brown solids M0S2CI2 and WS2C1214, ... [Pg.85]

Molybdenum(VI) oxytetrachloride Molybdenum(VI) oxytetrafluoride Molybdenum(V) oxytrichloride Molybdenum(III) sulfide Neodymium... [Pg.1149]

See other pages where Molybdenum oxytetrachlorid is mentioned: [Pg.227]    [Pg.228]    [Pg.228]    [Pg.670]    [Pg.54]    [Pg.55]    [Pg.55]    [Pg.227]    [Pg.228]    [Pg.228]    [Pg.670]    [Pg.54]    [Pg.55]    [Pg.55]    [Pg.196]    [Pg.727]    [Pg.719]    [Pg.196]    [Pg.703]    [Pg.801]    [Pg.773]    [Pg.765]    [Pg.799]    [Pg.719]   
See also in sourсe #XX -- [ Pg.215 , Pg.226 ]

See also in sourсe #XX -- [ Pg.215 , Pg.226 ]



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