Molybdenum complexes arylimido

Since adamantyfimido alkylidene complexes of molybdenum have been the catalysts of choice in some metathesis reactions, and since tungsten arylimido alkylidene complexes are often more selective for forming Z products than the analogous molybdenum complexes, a route to tungsten-based adamantyl and t-butyfimido catalysts was sought. 

MoOCl2(PMe2Ph)3] reacts with 1,2-disubstituted hydrazines, PhCONHNHR, (R = Ph, 1-naphthyl, p-MeO-QH, p-Me QH4, or p-Cl-C H ) to give the red. diamagnetic crystalline molybdenum-arylimido-complexes (91). The full reports of the crystal and molecular structures of... 

Molybdenum(Vl) complexes, 1256,1375-1414 alkyl, 1407 alkylidyne, 1407 alkylimido, 1396 arylimido, 1396 bipyridyldibromodioxo, 1388 bis(acetylacetonate) dioxo, 1388 catecholate dioxo, 1389 dimethyl, 1406 dinuclcar, 1408 IR spectroscopy, 1412 O or S bridge, 1411 preparation, 1411 Raman spectroscopy, 1412 single 0X0 bridge, 1408 structure, 1408 triple bridge, 1410 dioxo... 

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