Molybdenum and Iron Complexes Based on a Trithiolate Ligand

Department of Biological Chemistry, John Innes Centre, Colney Lane, Norwich NR4 7UH, UK [Pg.252]

Concurrent studies on nitrogenases, including those carried out by biochemists in the Unit at Sussex, revealed that they contain cofactors with significant quantities of molybdenum, iron and sulfur (later it was found that in some nitrogenases molybdenum is apparently replaced by vanadium or iron). Efforts were therefore made to develop the nitrogen chemistry of these metals with [Pg.252]

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