Modulation of polarization

As described above, there are two forms of vibrational optical activity, one derived from infrared absorption and the other from Raman scattering. Both forms involve the differential response of a molecule to the modulation of polarization of the interacting radiation between right and left circularly polarized states. In the case of infrared absorption, VCD is defined as die differential absorbance for left minus that for right circularly polarized infrared radiation. This is expressed by the relation ... 

In a motor-driven self-nuUing ellipsometer, the dc feedback currents are used to drive servomotors instead of being passed through the Faraday cell. As an alternative to the polarizer modulation described above, crystals with electro-optic effect (e.g., Pockels effect) can be used to modulate the relative phase retardation by an electric ac field. Independent modulations of polarizer... 

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