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Modifications of the Ideal Rubber Model

Besides the assumption of ideality inherent in Equation 9.61, several approximations were made in obtaining the force-extension relation of Equation 9.70. These assumptions are as follows  [Pg.393]

Individual chains between cross-links (strands) obey Gaussian statistics. [Pg.393]

The cross-links are fixed in space and deform affinely. [Pg.393]

The chains are all independent and do not interact with one another (phantom chain approximation). [Pg.393]

Several theoretical and empirical modifications of Equation 9.70 have been developed to improve the agreement between predictions and experimental results [24-26], Some of these modifications will now be discussed  [Pg.394]


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