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MnCu 2 • DMSO

MnCu(opba)(DMSO)3 structure, 43 196-197 zigzag chain structure, 43 198-199 MnCuCopbaKHiOlj DMSO, structure, 43 196 Mn[Cu(oxpn)l3 =+, 43 217 MnCulpbaOHXHjOlj magnetization versus temperature, 43 193, 195... [Pg.186]

Figure 3. Structure of the linear chain MnCu(opba)(H20)2-DMSO (top) and of the zigzag chain MnCu(opba)(DMSO)3 for clarity only the coordinating oxygen atoms of DMSO are represented (bottom). Figure 3. Structure of the linear chain MnCu(opba)(H20)2-DMSO (top) and of the zigzag chain MnCu(opba)(DMSO)3 for clarity only the coordinating oxygen atoms of DMSO are represented (bottom).
Two Mn(II)Cu(II) chain compounds have been obtained with the precursor [Cu(opba)] . The first is MnCu(opba)(H20)2 DMSO, with... [Pg.195]

Fig. 11. Structure of the zigzag chain compound MnCu(opba)(DMSO)3. Reprinted from Stumpf et at. (33). Copyright 1993 American Chemical Society. Fig. 11. Structure of the zigzag chain compound MnCu(opba)(DMSO)3. Reprinted from Stumpf et at. (33). Copyright 1993 American Chemical Society.
Heating MnCu(opba)(DMSO)3 to 140° under vacuum results in a product of which the stoichiometry is MnCu(opba) 0.7DMSO. This product behaves as an amorphous magnet below = 6.5 K. [Pg.197]

DMSO, but tetrachlorocobaltate(II) is capable of existence in this solvent, in which C0CI2 undergoes considerable autocomplex formation. Likewise manganese bromide is completely ionized in TMP, but MnCLa and [MnCU]"" are known to exist in TMP solutions again with autocomplex formation of MnCl2. [Pg.164]


See other pages where MnCu 2 • DMSO is mentioned: [Pg.41]    [Pg.42]    [Pg.196]    [Pg.197]   
See also in sourсe #XX -- [ Pg.41 ]




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