Mixed micellisation

The so-called thermodynamic-molecular models [18, 20-22] form another separate group of theories. For example, Puvvada and Blankschtein showed that the expression for the total free energy of mixed micellisation could be presented for binary surfactant mixture as follows... 

N. Nishikido, Thermodynamic models for mixed micellisation, in Mixed Surfactant Systems, Eds. K. Ogino and M. Abe, Surfactant science series, V. 46, Marcel Dekker,... 

Keywords p parameter electrostatic interaction mixed micellisation chelating surfactant amphoteric surfactant... 

However, it was observed that t)q)ical food reagents (salts, ethanol, or sugars) in the aqueous phase play a role in soluble LMWE micellisation and protein-LMWE interactions and, as a consequence, on the interfacial characteristics of the mixed films (Patino et al., 2003). 

R. Nagarajan, Micellisation of Binary Surfactant Mixtures Theory, in Mixed Surfactant Systems, P.M. Holland and D.N. Rubingh (Eds.), ACS Symposium Series 501, ACS, Washington, DC, 1992, pp. 54-95. 

Less common are the ABC copolymers with one middle polyelectrolyte and two hydrophobic blocks, whose self-assembly in water usually leads to the formation of flower-like micelles. Such micelles have been reported by Tsitsilianis et al. in the case of PS-PAA-P BMA [174] or P2VP-PAA-PnBMA at pH above 5 [31]. Finally, two more examples of the formation of mixed corona micelles are those observed from the micellisation of a PEO-PS-P4VP triblock copolymer studied by Chen et al. [175] or in the case of PEG-PnBA-PDMAEMA triblock investigated by Wrai etal. [176]. 

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