Miscellaneous Addition Reactions

The formation of benzimidazoles, benzoxazoles and benzthiazoles by the addition of 2-(NH2), 2-(0H) and 2-(SH) anilines to acyl chlorides in ionic liquids 

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N-Phenylselenophthalimide, 245 Additions involving selenium Benzeneselenenyl halides, 26 N-Phenylselenophthalimide, 245 Miscellaneous reagents Aluminum chloride, 15 Lithium bis(dimethylphenyl-silyl)cuprate, 161 Organotin reagents, 211 Addition reactions to carbonyl... 

This section will focus on reactions that exemplify the use of particular additives and cosolvents and on the origin of the beneficial effects of the additives. Miscellaneous additives, not included in the three categories above, that promote the reactivity of Sml2 will be discussed at the end of the section. Further examples of the use of additives and cosolvents can be found in subsequent chapters. 

C. Grignard-Type Addition Reactions of Miscellaneous Organozinc Compounds. ... 

The surfactant slurry, builders, and other miscellaneous additives are introduced in the crutcher. A considerable amount of water is removed, and the paste is thickened by the tripolyphosphate (used as a builder) hydration reaction ... 

Electrophilic Addition Other Addition Reactions Reduction of Unsaturated Steroids Oxidation and Dehydrogenation Miscellaneous Reactions... 

X. MISCELLANEOUS ADDITIONS AND ELIMINATIONS A. Reimer-Tiemann Reaction and Related Processes... 

Transition metal catalyzed asymmetric hydrocarboration reactions are addition reactions forming one C—C and one C—H bond. Prominent examples are hydrovinylation, hydroformylation, hydroacylation, hydrocarboxylation, and hydrocyanation. Various related conversions, such as hydroalkylation, hydroarylation, conjugate addition, reductive dimerization, and metal induced ene reactions are collected in Section 1.5.8.2.6. dealing with miscellaneous methods of this type. Some of these methods are not exclusively mediated by metal catalysts and therefore are also covered in other sections of this volume. 

For convenience, the reactions to be considered have been arbitrarily grouped into four categories displacement reactions, addition reactions, reactions with a,jS-imsaturated compounds, and miscellaneous reactions. 

Miscellaneous Reactions. 1.2.1 Addition Reactions - A novel photochemical reaction of stilbene in carbon tetrachloride solution has been described. Irradiation of this system populates the first excited singlet state of stilbene which then abstracts a halogen from the solvent. The resulting radical pair composed of a trichloromethyl radical and (14) yields the products. 

Other Miscellaneous Enantioselective Conjugate Addition Reactions... 

VI. Other Addition Reactions to Double Bonds Vn. Oxidation Reactions of Polymers Vin. Functionalization of Polymers IX. Miscellaneous Chemical Reactions of Polymers X. Block and Graft Copolymerization References... 

In conclusion, stilbenes involve in miscellaneous chemical reactions. For non-substituted stilbenes, the most chemically reactive part is double bond, which relatively easily undergoes the halogenation, epoxidation, oxidation, reduction, and addition. The chemistry of substituted stilbenes is in principle as rich as organic chemistry. Including stilbenes in dendrides, dextrins, polymers, and surfaces led to a sufficient change in their chemical, photochemical, photophysical, and mechanical properties and, therefore, establishes the basis for design of new materials. 

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