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Microwave-assisted Reactions on Graphite

Andre Laporterie, Julien Marqui , and Jacques Dubac [Pg.219]

Most forms of carbon, except diamond, which are renowned as supports for precious metal catalysts in certain applications [3], interact strongly with MW [4]. Amorphous carbon and graphite, in their powdered form, irradiated at 2.45 GHz, rapidly (within 1 min) reach very high temperatures ( 1300 K). This property has been used to explain MW-assisted syntheses of inorganic solids [5], In these syntheses carbon is either a secondary susceptor which assists the initial heating but does not react with other reactants, or is one of the reactants, e. g. in the synthesis of metal carbides. MW-carbon coupling has also been widely developed  [Pg.219]

Microwaves in Organic Synthesis. Edited by Andre Loupy [Pg.219]

Copyright 2002 WILEY-VCH Verlag GmbH Co. KGaA,Weinheim [Pg.219]

The MW-promoted cracking of organic molecules in the presence of silica-supported graphite [10 a] or activated charcoal [10 b] has also been reported. [Pg.220]


Laporterie A, Marquie J, Dubac J (2002) Microwave-assisted Reactions on Graphite. In Loupy A (ed) Microwaves in Organic Synthesis. Wiley, Weinheim, p 219... [Pg.102]


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