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Methylmagnesium bromide, conjugate addition

Methylmagnesium iodide reacts with the 3-carbonyl group of 243 and gives rearranged product 81. When phenylmagnesium bromide is used instead, conjugate addition occurs (Scheme 31) <1994T5037>. [Pg.638]

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Conjugate additions bromide

Methylmagnesium

Methylmagnesium bromide

Methylmagnesium bromide addition