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Methyl 3-eleostearate

Hilditch and Pathak (58) studying the catalytic reduction of methyl eleostearate, found that the reaction at 110° and at 170° was extremely selective in the presence of Raney nickel. No methyl stearate was formed until 90% of the linoleate had been transformed into octadeceno-ates. Ehrhart (59) used Raney nickel to hydrogenate compounds of the type RCH(CN)NHCOR The nitrile was reduced to the amine, but the amide was untouched. [Pg.425]

A hydroboration-protonolysis procedure for the conversion of conjugated enynes to dienes is far superior to partial hydrogenation over Lindlar s catalyst, in terms of stereoselectivity and yields280. Ratovelomanana and Linstrumelle reported the synthesis of methyl a-eleostearate (equation 163) and methyl punicate by employing this strategy280. [Pg.454]

Hydrogenation of methyl p-eleostearate (methyl frani,fran5,fra s-9,ll,13-octadecatrienoate) with [Cr(CO)3(arene)] yields the diene products from 1,4-addition trans-9-cis- 2- and CK-10-fran5-13-oc-tadecadienoates). With a-eleostearate (methyl d5,fran5,fra i-9,ll,13-octadecatrienoate), stereoselective 1,4-reduction of the trans,trans-diene moiety yields linoleate (cis,cis-9,l2) accompanied by cm,Irani-1,4-dienes which are formed from the isomerization of a- to p-eleostearate. ... [Pg.451]

We have used silica gel TLC to separate conjugated triglycerides and methyl esters from the non-conjugated species in the seeds of Momordica charantia and Trichosanthus anguina (unpublished results). These seeds contain between 50%-60% of their total fatty acids as a-eleostearic and punicic... [Pg.3]

Yurawecz et al. (1993) found traces (up to 0.2%) of conjugated linolenic acid (CLN) in vegetable oils in their study of 27 oils for CLN content by ultraviolet (UV) measurement. The isomers were identified as a-eleostearic acid (9cis(c),lltrans (t),13t-18 3), P-eleostearic acid (9t,llt,13t-18 3) and 8t,10t,12t-18 3. HPLC analysis of purified soyabean oil methyl esters indicates the presence of small amounts of CLA... [Pg.305]


See other pages where Methyl 3-eleostearate is mentioned: [Pg.86]    [Pg.897]    [Pg.897]    [Pg.897]    [Pg.897]    [Pg.108]    [Pg.617]    [Pg.101]    [Pg.183]    [Pg.90]    [Pg.21]    [Pg.45]    [Pg.50]   


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Methyl (3-eleostearate hydrogenation

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