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Methoxy radicals, from decomposition

Hoare and Wellington (22) produced CH3O radicals from the photochemical (50° and 100°C.) and thermal (135°C.) decompositions of di-terf-butyl peroxide in the presence of 02. The initially formed tert-butoxy radicals decomposed to acetone plus methyl radicals, and the methyl radicals oxidized to methoxy radicals. Formaldehyde and CH3OH were products of the reaction the formation of the former was inhibited, and the latter was enhanced as the reaction proceeded. If the sole fate of CH3O were either... [Pg.37]

See other pages where Methoxy radicals, from decomposition is mentioned: [Pg.9]    [Pg.438]    [Pg.157]    [Pg.291]    [Pg.213]    [Pg.508]    [Pg.312]    [Pg.137]    [Pg.155]    [Pg.382]    [Pg.496]    [Pg.182]    [Pg.698]    [Pg.357]    [Pg.263]    [Pg.1250]    [Pg.147]    [Pg.155]    [Pg.357]    [Pg.1743]    [Pg.1967]    [Pg.117]    [Pg.56]    [Pg.182]   


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Decomposition radical

From decomposition

Methoxy decomposition

Methoxy radicals, decomposition

Radicals from

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