2- Methoxy-4-allylphenol

A second hydroxyl or methoxyl substituent is often present 2-methoxy-4-allylphenol and 2-methoxy-4-propenylphenol are the most important compounds belonging to this category. 

Ethyl phenylacetate <60.5 Ethyl salicylate 103.5 Eugenol( 2-Methoxy-4-allylphenol)<59.5 Eugenol methyl ether <61.5... 

SYNS 4-ALLYLGUAtACOL 4-ALLYL-l-HYDROXY-2-METHOXYBENZENE 4-ALLYL-2-METHOXYPHENOL CARYOPHYLLIC ACID EUGENIC ACID Fa 100 FEMA No. 2467 1-HYDROXY-2-METHOXY-4-ALLYLBENZENE 4-HYDROXY-3-METHOXYALLYLBENZENE 1-HYDROXY-2-METHOXY-4-PROP-2-ENYLBENZENE 2-METHOXY-4-ALLYLPHENOL 2-METHOXY-4-PROP-2-ENYLPHENOL 2-METHOXY-4-(2-PROPENYL)PHENOL 2-METOKSY-4-ALULOFENOL (POUSH) NCI-C50453 SYNTHETIC EUGENOL... 

METHOXY-4-ALLYLPHENOL see EQR500 2-METHOXY-l-AiMINOBENZENE see AOV900 2-METHOXY-l -AMINOBENZENE HYDROCHLORIDE see AOX250 2-METHOXYAMUNE see A0 900... 

Synonyms Allylguaiacol 4-Allylguaiacol 4-Allyl-1-hydroxy-2-methoxybenzene 4-Allyl-2-methoxyphenol Caryophyllic acid Eugenic acid 1-Hydroxy-2-methoxy-4-allylbenzene 4-Hydroxy-3-methoxyallylbenzene 1 -Hydroxy-2-methoxy-4-prop-2-enylbenzene 2-Methoxy-4-allylphenol 2-Methoxy-4-(2-propenyl) phenol 2-Methoxy-4-prop-2-enylphenol Phenol, 2-methoxy-4-(2-propenyl)-... 

Methoxy-4-allylphenol. See Eugenol Methoxyamine, hydrochloride. See o-Methylhydroxylamine hydrochloride 2-Methoxy-1-aminobenzene. See o-Anisidine 4-Methoxy-1-aminobenzene. See p-Anisidine 2-Methoxy-1-aminobenzene hydrochloride. See o-Anisidine hydrochloride 4-Methoxy-1-aminobenzene hydrochloride. See p-Anisidine hydrochloride 6-Methoxy-2-aminobenzothiazole. See 2-Amino-6-methoxybenzothiazole... 

Electrochemical oxidation of 2,6-dimethoxy-4-allylphenol in aqueous methanol buffered with sodium hydrogen carbonate gives similar amounts of 2- and 4-methoxy substitution products, fhe 2-methoxylated product readily undergoes a Diels-Alder reaction with itself. The dimer 19, the natural product asatone, is found in some 1 % yield and most of the 2-methoxylated product is lost by addition of the ally alkene bond across the diene system of a second molecule [109]. 

Another occasionally useful transformation of allylphenols is the isomerization to propenylphenols by strong alkali, as in the well-known isomerization of eugenol to isoeugenol. For example, 2-methoxy-6-allylphenol (LXXI) is changed to the propenyl compound LXXII by... 

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