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Metallaboranes metal-rich

Recently three discrete transition metal borides have been prepared and structurally characterized. These metal-rich metallaboranes con-... [Pg.222]

Most metallaboride clusters are synthesized from metal-rich metallaboranes (Lewis base adducts of BH3 are often used as the source of the B atom) several different methods are used to transform B-H bonds into B-M interactions and hence isolate a naked boron atom. Two recent review articles have been devoted to this subject.l l... [Pg.894]

Metallaboranes mirror the metal hydrocarbyl complexes of organometallic chemistry and offer the promise of a similar rich chemistry.1 Indeed there are a number of strictly isoelectronic borane and hydrocarbon complexes in which a C atom is formally replaced with a B or BH moiety.2 Comparison of the structure and properties of these compound pairs highlights interesting similarities and differences between the organic and inorganic derivatives.3... [Pg.255]

See other pages where Metallaboranes metal-rich is mentioned: [Pg.31]    [Pg.157]    [Pg.159]    [Pg.199]    [Pg.222]    [Pg.24]    [Pg.1715]    [Pg.144]    [Pg.29]    [Pg.10]    [Pg.458]    [Pg.136]    [Pg.157]    [Pg.103]    [Pg.32]    [Pg.185]   
See also in sourсe #XX -- [ Pg.222 , Pg.223 , Pg.224 , Pg.225 ]



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