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Metal self-assembly versus

Figure 5.2 Tafel plots of In k versus overpotential for a mixed self-assembled monolayer containing HS(CH2)i600C-ferrocene and HS(CH2)isCH3 in 1.0 M HCIO4 at three different temperatures V, 1 °C O/ 25 °C , 47°C. The solid lines are the predictions of the Marcus theory for a standard heterogeneous electron transfer rate constant of 1.25 s-1 at 25 °C, and a reorganization energy of 0.85 eV (= 54.8 kj moh1). Reprinted with permission from C. E. D Chidsey, Free energy and temperature dependence of electron transfer at the metal-electrolyte interface, Science, 251, 919-922 (1991). Copyright (1991) American Association for the Advancement of Science... Figure 5.2 Tafel plots of In k versus overpotential for a mixed self-assembled monolayer containing HS(CH2)i600C-ferrocene and HS(CH2)isCH3 in 1.0 M HCIO4 at three different temperatures V, 1 °C O/ 25 °C , 47°C. The solid lines are the predictions of the Marcus theory for a standard heterogeneous electron transfer rate constant of 1.25 s-1 at 25 °C, and a reorganization energy of 0.85 eV (= 54.8 kj moh1). Reprinted with permission from C. E. D Chidsey, Free energy and temperature dependence of electron transfer at the metal-electrolyte interface, Science, 251, 919-922 (1991). Copyright (1991) American Association for the Advancement of Science...
See other pages where Metal self-assembly versus is mentioned: [Pg.529]    [Pg.362]    [Pg.548]    [Pg.2741]    [Pg.2929]    [Pg.530]    [Pg.1634]    [Pg.205]    [Pg.597]    [Pg.6327]    [Pg.65]    [Pg.3560]    [Pg.310]    [Pg.310]    [Pg.59]    [Pg.215]    [Pg.371]    [Pg.246]    [Pg.373]   
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