Metal cont oxides

Conte, V., Di Furia, F. and Modena, G. (1992). Transition Metal Catalyzed Oxidation. The Role of Peroxometal Complexes, in Ando, W. (ed.). Organic Peroxides. John Wiley Sons, Chichester, pp. 559-598. 

V. Conte, F. Di Furia, Catalytic oxidations with hydrogen peroxide as oxidant. Peroxometal complexes derived from hydrogen peroxide. Some applications in organic synthesis. Catalysis by Metal Complexes 9 (1992) 223-252. 

In order to minimise possibilities for spurious metal-support effects associated in the literature with use of RliCh as precursor of ceria-dispersed rhodium [5], the materials used in the present study were prepared using rhodium(in) acetylacetonate (Aldrich) as precursor. Wet impregnation at 0.5, 2 or 4 wt% onto the surfaces of the oxide powders was achieved from solution in high purity methanol or tetrahydrofuran, after which samples were dried and calcined in O2 for 2 hr at 823 K. Ceria available from Aldrich (Ce02(A), 16 m ) or Rhone-Poulenc (Ce02(r.p.),110 m g ), and AI2O3 (Conte, 200 m g ) were used as supports. 

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