Metal complexes, the nucleophilicity of towards organic molecules

Metal complexes, the nucleophilicity of towards organic molecules, 23,1 Methyl transfer reactions, 16,87... [Pg.338]

The Nucleophilicity of Metal Complexes Towards Organic Molecules... [Pg.49]

This review will concentrate on the detailed mechanistic study of the reactions between metal-complex nucleophiles and organic molecules including the stereochemical consequences of the reactions at both the carbon centre (Sections 6 and 7) and the metal (Sections 8 and 9). Furthermore, the influence of substituents on the carbon centre (Sections 11 and 12) and the nature of the solvent (Section 5) will be discussed. However, neither the nucleophilicity of ligands towards organic substrates nor the synthesis of nucleophilic complexes will be covered. The reader interested in the latter is recommended to the reviews by King (1975) and Vaska (1968). [Pg.2]

Before discussing in detail the nucleophilicity of metal complexes towards organic molecules it is important to appreciate the depth of reactivity types that is being considered. Predominantly the organic substrates are alkyl halides and tosylates, acyl halides, aryl halides and allyl halides together with a limited amount of information of the interactions with propargyl halides, and epoxides. [Pg.5]

The nucleophilicity of transition metal complexes towards organic molecules has found application in industrial catalysts. [Pg.55]

See also in sourсe #XX -- [ Pg.23 ]

See also in sourсe #XX -- [ Pg.23 ]

See also in sourсe #XX -- [ Pg.23 ]

See also in sourсe #XX -- [ Pg.23 ]

See also in sourсe #XX -- [ Pg.23 ]

See also in sourсe #XX -- [ Pg.23 ]

See also in sourсe #XX -- [ Pg.23 ]

See also in sourсe #XX -- [ Pg.23 ]

See also in sourсe #XX -- [ Pg.23 ]

See also in sourсe #XX -- [ Pg.23 ]

See also in sourсe #XX -- [ Pg.23 ]

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