Metal Complexes of Sulfimido, and Sulfenamido Anions

10 Metal Complexes of Sulfimido, [Pli2S=N], and Sulfenamido, [RSNR ] , Anions 

Complexes of the sulfenamido anion [RSNR ] with several transition metals [Zr(IV), Ti(IV), Mo(VI), W(Vf), Ni(If), and U(IV)] are known.They are prepared by the reaction of the lithium derivative of the sulfenamido anion with a metal halide complex. A selenium complex W(N Bu)2( BuNSePh)2 has been obtained in a similar 

Maaninen, El. M. Tuononen, G. Sebatte, R. Suontamo, J. Valkonen, R. Laitinen 

Bjorgvinsson, H. W. Roesky, C. Freire-Erdbriigger and G. M. Sheldrick, J. Chem. Soc., Dalton Trans., 811 (1993). 

Schatte, T. Chivers, C. Jaska and N. Sandblom, Chem. Commun., 1657 (2000). 

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