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Metal complexes—continued oxidation-reduction potentials

Bipyridyl (continued) as ligand, 12 135-1% catalysis, 12 157-159 electron-transfer reactions, 12 153-157 formation, dissociation, and racemization of complexes, 12 149-152 kinetic studies, 12 149-159 metal complexes with, in normal oxidation states, 12 175-189 nonmetal complexes with, 12 173-175 oxidation-reduction potentials, 12 144-147... [Pg.24]

The coverage in this chapter is not comprehensive and no tabulation of rate data has been attempted. A more extensive account of the material will appear in Volume 9 of the series the presentation of the material also differs slightly from previous volumes. There have been many important developments in this general area. A comprehensive review of one-electron reduction potentials for nonmetallic substrates has appeared. Detailed kinetic studies have been reported for several important reactions where metal ions serve as catalysts in the transformation of organic substrates.Catalytic oxidation reactions involving metal complexes and macrocyclic metal complexes have been reviewed. Continued interest centers on catalysis by metalloporphyrins, and the role of metal complexes in electrocatalytic reductions has been reviewed. ... [Pg.32]

The NO/NO+ and NO/NO- self-exchange rates are quite slow (42). Therefore, the kinetics of nitric oxide electron transfer reactions are strongly affected by transition metal complexes, particularly by those that are labile and redox active which can serve to promote these reactions. Although iron is the most important metal target for nitric oxide in mammalian biology, other metal centers might also react with NO. For example, both cobalt (in the form of cobalamin) (43,44) and copper (in the form of different types of copper proteins) (45) have been identified as potential NO targets. In addition, a substantial fraction of the bacterial nitrite reductases (which catalyze reduction of NO2 to NO) are copper enzymes (46). The interactions of NO with such metal centers continue to be rich for further exploration. [Pg.220]

See other pages where Metal complexes—continued oxidation-reduction potentials is mentioned: [Pg.377]    [Pg.313]    [Pg.327]    [Pg.327]    [Pg.45]    [Pg.144]    [Pg.72]    [Pg.74]    [Pg.3971]    [Pg.6626]    [Pg.174]    [Pg.85]    [Pg.340]    [Pg.555]    [Pg.250]    [Pg.174]    [Pg.147]    [Pg.1043]    [Pg.146]    [Pg.3]    [Pg.293]    [Pg.388]    [Pg.174]   
See also in sourсe #XX -- [ Pg.147 ]

See also in sourсe #XX -- [ Pg.147 ]



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Complex metal oxides

Complex potential

Complexes reduction

Complexity reduction

Continuous oxidation

Metal complexes reduction

Metal complexes—continued

Metal complexes—continued oxidation

Metal complexes—continued reduction

Metal potential

Metals continued

Metals oxidation potentials

Metals reduction potentials

Oxidation potential

Oxidation-reduction complexes

Oxidation-reduction potential

Oxidation—continued

Oxidization-reduction potential

Oxidizing potential

Reduction continued)

Reduction continued) potentials

Reduction potentials metal oxidants

Reduction potentials oxidants

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