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Metal complexes—continued

Electron counting, in transition metal complexes (continued) and MLX plots, 1, 36 via neutral ligand formalism, 1, 4 overview, 1, 2... [Pg.101]

The catalytic activity of Hg in elimination and substitution reactions of transition-metal complexes continues to be the subject of study. Kinetic studies on the Hg" catalysed aquation of both cis-[Co(en)2(CN)Cl], cis-[(chloro)(aniline)CO(en)2], and [PdLX] (L = tetramethyldiethylenetriamine X = Cl, Br, or I) are consistent with intermediate adduct formation at the halide substituent. Mercury(ii) reacts reversibly with the [Co(NH3)5SCN] ion to yield [Co(NH3)5(SCN)Hg] which irreversibly undergoes either aquation to yield [Co(NH3)sH20] or isomerization to yield [Co(NH3)5(NCS)Hg] at approximately equal rates. The kinetics of the reaction... [Pg.422]

The catalysis of DNA cleavage by metal complexes continues to be of interest. Reports of DNA cleavage by lanthanide complexes and cobalt(III) complexes have appeared this year. ... [Pg.226]

Carbon-Carbon Bond-forming Reactions via Organometal1ic Electrophilies. - Functionalization of unsaturated hydrocarbons by nucleophilic attack on their metal complexes continues to receive attention. Sequential double nucleophilic addition to a cationic cobalt complex of butadiene... [Pg.401]

Carbon-carbon bond formation by the addition of soft nucleophiles such as malonate enolates to 7r-allyl metal complexes continues to be a productive area. Various neutral tt-ally 1-iron complexes can be used to prepare esters (85) in this way while the tetracarbonyliron complex of methyl a-chloroacrylate undergoes a double addition to give polyester (86). Trost s group has shown that TT-ally 1-palladium complexes react completely stereoselectively as, for example, in the conversion of butyrolactone (87) into the tricarboxylate (88). ... [Pg.113]

See other pages where Metal complexes—continued is mentioned: [Pg.57]    [Pg.240]    [Pg.356]    [Pg.358]    [Pg.360]    [Pg.362]    [Pg.364]    [Pg.366]    [Pg.368]    [Pg.370]    [Pg.372]    [Pg.374]    [Pg.376]    [Pg.378]    [Pg.225]    [Pg.529]    [Pg.196]    [Pg.279]    [Pg.488]    [Pg.148]    [Pg.538]    [Pg.107]    [Pg.538]    [Pg.232]   


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Azines—continued complexes with metal ions

Metal complexes—continued kinetic studies

Metal complexes—continued oxidation

Metal complexes—continued oxidation-reduction potentials

Metal complexes—continued oxidation-reduction reactions

Metal complexes—continued reduction

Metal complexes—continued spectroscopic studies

Metal complexes—continued stability constants

Metal complexes—continued substitution reactions

Metals continued

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