Metal complexes cont

Figure 3.31 As (due to orientational response of aqueous solvent) versus e, calculated for ET in a large binuclear transition metal complex (D (Ru2+/3+) and A (Co2+/3+) sites bridged by a tetraproline moiety) molecular-level results obtained from a nonlocal polarization response theory (NRFT, solid lines) continuum results are given by dashed lines, referring to numerical solution of the Poisson equation with vdW (cont./vdW) and SAS (cont./SAS) cavities, or as the limit of the NRFT results when the full k-dependent structure factor (5(k)) is replaced by 5(0) 5(k) for bulk water was obtained from a fluid model based on polarizable dipolar spheres (s = 1.8 refers to ambient water (square)). For an alternative model based on TIP3 water (where, nominally, 6 = ), ambient water corresponds to the diamond. (Reprinted from A. A. Milishuk and D. V. Matyushov, Chem Phys., 324, 172. Copyright (2006), with permission from Elsevier).

V. Conte, F. Di Furia, Catalytic oxidations with hydrogen peroxide as oxidant. Peroxometal complexes derived from hydrogen peroxide. Some applications in organic synthesis. Catalysis by Metal Complexes 9 (1992) 223-252. 

Reactions Between Two Metal Complexes Table 1 cont.)... 

Metal carbonyls and olefin complexes (published before 1950) (cont d)... 

TABLE 4 Oligomeric R Cluster Complexes with Endohedral Transition Metal Atoms T—Cont d Oligomer... 

Conte, V., Di Furia, F. and Modena, G. (1992). Transition Metal Catalyzed Oxidation. The Role of Peroxometal Complexes, in Ando, W. (ed.). Organic Peroxides. John Wiley Sons, Chichester, pp. 559-598. 

---