Metal complex compds

Cobalt oxide 26,463 Colman s. Gabriel Complex compds. s. a. Metal complex compds. 

F.Ephraim, Ber 46, 3103-31(1913) CA 8, 597 (1914) (The nature of residual valence influence of the anion on the stability of complex cations in metal ammonia compds) 7)... 

Uses Catalyst and/or source of fluorine in fluorination reactions prep, of org. fluorine compds. replacement of chlorine by fluorine in chlorinated hydrocarbons prod, of complex compds. with other metals and halogens Manuf./Distrib. Aldrich http //www.sigma-aidrich.com, Alfa Aesar http //www.aifa.com, Atofi na http //www.atofinachemicais.com, Atomergic Chemetals http //www.atomergic.com, Fluka http //www.sigma-aidrich. com Honeywell Perf. Polymers http //WWW. honeyweiippe. com, http //WWW.honeyweii-piastics.com, Noah http //www.noahtech.com. Spectrum Quality Prods. http //www.spectrumchemicai. com Antimony pentasulfide CAS 1315-04-4 EINECS/ELINCS 215-255-5 UN 1549... 

Uses Catalyst with aluminum alkyls as a Ziegler-Natta polymerization catalyst in synthesis of wide range of early-transition-metal complexes and organometallic compds. 

Sakaki S (1990) Transition-metal complexes of nitrogen, carbon dioxide, and similar small molecules. Ab-initio MO studies of their stereochemistry and coordinate bonding nature. Stereochem Organomet Inorg Compd 4 95-177... 

G. A. Tolstikov and U. M. Dzhemilev, Synthesis of Heterocyclic Compounds in the Presence of Transition Metal Complexes , Chem. Heterocycl. Compd., 1980,16, 99. 

Occurs in milk and other biol. systems. Key compd. involved in biosynth. of nucleic acid pyrimidine bases. Shows bacteriostatic and cytostatic props. Forms metal complexes. Uricosuric agent. Used in photometric detn. of Zn. Cryst. (H2O). Mp 322-325°, Mp 345-346°. 

E++02, etc where E is an element. The metallic atoms are bonded to the oxygen bridge with ionic bonding. For convenience, differentiation is made between simple and complex inorganic peroxide compds. According to VoPnov (Ref 5) simple peroxide compds also... 

Levason, W., Phosphine complexes of transition metals in Chem. Organophosphorous Compd. Hartley, F. R., Eds. Wiley Chichester, 1990, p 567. 

Zaluska, A., and L. Zaluski, New catalytic complexes for metal hydride systems, /. Alloys Compd., 404-406, 706-711,2005. 

L. Zaluski, A. Zaluska, J.O. Strom-Olsen, Hydrogenation properties of complex alkali metal hydrides fabricated by mechano-chemical synthesis , J. Alloys Compd. 290 (1999) 71-78. 

M. Schwarz, A. Haiduc, H. Still, P. Paulus, H. Geerlings, The use of complex metal hydrides as hydrogen storage materials Synthesis and XRD-studies of CaiAlH ) and MgiAlH ) , J. Alloys Compd. 404 06 (2005) 762-765. 

In naming the complexes, the constituents of the nucleus are taken first(starting with the acid radical or extra neutral radical, if any present, and followed by the neutral group and metal) and then comes the name of the radical outside the bracket. For instance, the compd [Co(NH,)y Cl] (NO, )2 is called "c hi oro pent am mine cobalt (III) nitrate and the compd [Co(NH,)g HaO](NO,), is "aquopentamminecobalt (III) nitrate , etc... 

---